Universitat Rovira i Virgili

A. Polo, E. Fernández, C. Claver, S. Castillón
Hydroformylation of glucal derivatives with rhodium catalysts. Crucial influence of the auxiliary ligand tris(ortho-tert-butylphenyl)phosphite.
Journal of Chemistry Society, Chemical Communications, 1992, 639

E. Fernández, S. Castillón.
Synthesis of acetals from alkenes by one-pot hydroformylation-transacetalization reactions catalysed by rhodium complexes and pyridinium p-toluenesulphonate
Tetrahedron Letters, 1994, 35, 2361

E. Fernández, A. Ruíz, S. Castillón, C. Claver, J. F. Piniella, A. A. Larena, G. Germain
Preparation, structure and reactivity of dinuclear aminothiolate-bridged Iridium complexes.
Journal of Chemical Society, Dalton Transactions, 1995, 2137

R. B. Bedford, S. Castillón, P. A. Chaloner, C. Claver, E.Fernández, P. B. Hitchcock, A. Ruíz.
Iridium complexes of orthometallated triarylphosphites: synthesis, structure, reactivity and their use as imine hydrogenation catalysts.
Organometallics, 1996, 15, 3990

E. Fernández, M. W. Hooper, F. I. Knight, J. M. Brown.
Catalytic asymmetric hydroboration-amination.
Chemical Communications, 1997, 173

M. W. Hooper, E. Fernández, J. M. Brown.
Novel synthetic applications of catecholborane derivatives
Abstracts of papers of the American Chemical Society, Washington: American Chemical Society, 1997, 213:124-ORGN Part 2

E. Fernández, A. Ruíz, C. Claver, S. Castillón, A. Polo, J. F. Piniella, A. Alvarez-Larena.
Regio- and stereoselective hydroformylation of glucal derivarives with rhodium catalysts.
Organometallics, 1998, 17, 2857

E. Fernández, A. Polo, A. Ruíz, C. Claver, S. Castillón.
Consecutive catalytic hydroformylation-acetalization of glucal derivatives with rhodium-phosphite and pyridinium toluene-p-sulfonate as catalysts. the influence of protecting groups.
Chemical Communications, 1998,1803

H. Doucet, E. Fernández, T. P. Layzell , J. M. Brown.
The scope of catalytic asymmetric hydroboration / oxidation with rhodium complexes of 1,1'-(2-diarylphosphino)isoquinolines
Chemistry: A European Journal, 1999, 5, 1320

E. Fernández, A. Ruíz, C. Claver, S. Castillón, P. A. Chaloner, P. B. Hitchcock.
The synthesis and single-crystal X-ray structure of the first mononuclear iridium carbonyl hydride with two othometallated phosphite ligands, cis-[IrHCO{P(O-o-tBuC6H3)(O-o-tBuC6H4)2}2]
Inorganic Chemistry Communications, 1999, 2, 21

R. Margalef-Català, P. Salagre, E. Fernández, C. Claver.
High efficiency and reusability of iridium complexes adsorbed in montmorillonite clay on catalytic hydrogenation of imines.
Catalysis Letters, 1999, 60, 121

E. Fernández, A. Ruíz, C. Claver, S. Castillón, P. A. Chaloner, P. B. Hitchcock
Synthesis and structural determination of the stable dinuclear carbonyl-phosphite rhodium (0) complex (CO)2(P(O-o-tBuC6H4))Rh-Rh(P(O-o-tBuC6H4))(CO)3.
Lugar de publicación: Inorganic Chemistry Communications, 1999, 2, 283

E. Fernández, C.Bo, J. M. Poblet.
How the electronic and steric properties of the ligand can determine the stability of the asymmetric carbonyl-phosphite Rh(0) complex (CO)2(P(O-o-tBuC6H4))Rh-Rh(P(O-o-tBuC6H4))(CO)3
Inorganic Chemistry Communications, 2000, 2, 19

A. Martorell, C. Claver, E. Fernández*.
The influence of chiral phosphite and phosphonite ligands on the hydrogenation of imines with rhodium and iridium complexes.
Inorganic Chemistry Communications, 2000, 2, 132

E. Fernandez, K. Maeda, M. W. Hooper, J. M. Brown.
Catalytic asymmetric hydroboration/amination and alkylamination with rhodium complexes of 1,1'-(2-diarylphosphino-1-naphthyl)isoquinoline.
Chemistry: A European Journal, 2000, 6, 1840

R. Margalef-Català, C. Claver, P. Salagre, E. Fernández*
Heterogenised iridium complexes for the asymmetric hydrogenation of imines.
Tetrahedron: Asymmetry, 2000, 11, 1476

C.Claver, E. Fernández, A. Gillón, K. Heslop, D. J. Hyett, A. Martorell, A. G. Orpen, P. G. Pringle.
Biarylphosphonites: a class of monodentate phosphorous (III) ligands that outperform their chelating analogues in asymmetric hydrogenation catalysis.
Chemical Communications, 2000, 961.

P. Uriz, E. Fernández*, N. Ruiz, C. Claver
Asymmetric hydroformylation of vinylarenes with rhodium-diphosphite catalysts.
Inorganic Chemistry Communications, 2000, 515.

R. Margalef-Català, C. Claver, P. Salagre, E. Fernández*
Functionalization of amines by "one pot - free solvent" reductive alkylation with a recyclable catalyst.
Tetrahedron Letters, 2000, 41, 6583.

E. Fernández, A. Gillon, K. Heslop, E. Horwood, D. J. Hyett, A. G. Orpen, P. G. Pringle.
Rationally designed improvement of the bis(phospholano)ethane ligand for asymmetric hydrogenation leads to a reappraisal of the factors governing the enantioselectivit of Duphos catalysts.
Chemical Communications, 2000, 1663.

C. Claver, E. Fernández,* R. Margalef-Català, F. Medina, P. Salagre, J. E. Sueiras
Studies on the characterisation of several iridium- and rhodium - clay catalysts and their activity in imine hydrogention
Journal of Catálisis, 2001, 201, 70

A. M. Segarra, R. Guerrero, C. Claver, E. Fernández*
An unprecedented recyclable catalysts system for asymmetric hydroboration
Chemical Communications, 2001, 1808.

P. Uriz, M. Serra, P. Salagre, S. Castillon, C. Claver, E. Fernández*
A new and efficient catalytic method for synthesizing isocyanates from carbamates
Tetrahedron Letters, 2002, 43, 1673